滨海小流域表层沉积物多环芳烃污染特征及风险评估—以厦门后溪流域为例
DOI:
作者:
作者单位:

集美大学

作者简介:

通讯作者:

中图分类号:

基金项目:

国家自然科学(41576085);福建省自然科学(2023J01794)


Pollution Characteristics and Risk Assessment of Polycyclic Aromatic Hydrocarbons in Surface Sediments of Coastal Small Watersheds: A Case Study of the Houxi Watershed in Xiamen
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    为揭示滨海小流域多环芳烃(PAHs)的污染特征及生态风险,本研究选取厦门后溪流域为研究对象,系统采集了18个点位的表层沉积物样品,采用气相色谱-质谱联用技术(GC-MS)对16种PAHs进行定量分析。结果表明:研究区域Σ16PAHs总量为115.02~807.27 ng/g(均值371.33 ng/g)。组分以4环和5环占比最大,均超过25%;2环占比最小,不到4%;3环和6环占比居中,约为20%。空间分布呈现显著梯度特征,上游(A区)含量最低(86.23~153.61 ng/g),中游(B区)次之(298.23~456.71 ng/g),下游(C区)最高(435.24~656.11 ng/g),表明人类活动强度越大,PAHs污染程度也越高。基于沉积物质量基准法(SQGs)的生态风险评估显示,大部分的采样点位风险值介于最低级的罕见效应(REL)和次低级的临界效应(TEL)之间,少部分点位达到中级的偶然效应阈值(OEL),未出现较高级的可能效应(PEL)和最高级的频繁效应(FEL)风险等级。研究表明,后溪流域PAHs整体生态风险处于可控范围,但不同点位和不同类型多环芳烃的生态风险存在一定差异,需要引起关注。本研究为滨海城市小流域污染溯源及生态风险管理提供了科学依据。

    Abstract:

    In order to explore the pollution characteristics and ecological risks of polycyclic aromatic hydrocarbons (PAHs) in coastal small watersheds, surface sediment samples were collected from the Houxi River in Xiamen and analyzed by gas chromatography - mass spectrometry (GC - MS). The results showed that the total content of 16 PAHs in the surface sediments of the Houxi River watershed in Xiamen ranged from 115.02 to 807.27 ng/g, with an average of 371.33 ng/g. Among them, 4 - ring and 5 - ring PAHs had the largest proportion, 2 - ring PAHs had the smallest proportion, and 3 - ring and 6 - ring PAHs were in the middle. Comparing the average content of PAHs at each sampling point, the upstream (A) had the lowest value (86.23 - 153.61 ng/g), the middle reaches (B) were in the middle (298.23 - 456.71 ng/g), and the downstream (C) had the highest value (435.24 - 656.11 ng/g), indicating that the PAHs value was directly related to the regional ecological environment. The ecological risk of PAHs was evaluated by the sediment quality guidelines (SQGs). The results of the ecological risk assessment at most sampling points were between the lowest - level Rare Effect Level (REL) and the second - lowest - level Threshold Effect Level (TEL), and a small part was at the medium - level Occasional Effect Level (OEL). None of the stations reached the threshold ranges of the higher - level Probable Effect Level (PEL) and the highest - level Frequent Effect Level (FEL). This indicates that the overall ecological risk of PAHs in the surface sediments of the Houxi River watershed in Xiamen is low. However, there are certain differences in the ecological risks of different sampling points and different types of PAHs, which deserve attention. The research results can provide support for regional pollution prevention, control and risk assessment.

    参考文献
    相似文献
    引证文献
引用本文
分享
文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:2025-03-18
  • 最后修改日期:2025-06-03
  • 录用日期:2025-06-04
  • 在线发布日期:
  • 出版日期: