麦麸纤维素与腐植酸复合保水剂的制备及性能
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兰州城市学院2017年度青年教师科研项目(LZCU-QN2017-24)


Synthesis and Property of Superabsorbent Compound of Cellulose Extracted from Wheat Bran with Humic Acid
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    摘要:

    [目的]研究利用麦麸提取的纤维素与腐植酸共聚制备复合保水剂的方法及其性能,以解决现有保水剂生物难降解,成本高,污染大,再生性能差等问题。[方法]采用碱法从麦麸中提取纤维素,首次与腐植酸、丙烯酸水溶液聚合制备了复合保水剂。用扫描电子显微镜(SEM)、热重分析(TG)分别对树脂的表面形貌、热稳定性进行了表征,考查了NaOH、引发剂、交联剂、麦麸、腐植酸用量对复合保水剂吸水率的影响,并对温度、不同交联剂、再生性能进行了探讨。[结果]麦麸质量0.15 g,丙烯酸20 ml,交联剂(N,N-亚甲基双丙烯酰胺)的质量是丙烯酸质量的0.03%,引发剂的质量是丙烯酸质量的0.8%,腐植酸0.1 g,NaOH浓度80%,温度80℃时,吸水倍率最高,蒸馏水达到了989 g/g,对地下水的吸水倍率达到了120.34 g/g。对盐水的吸水倍率达到了62.76 g/g。[结论]实验方法制备的保水剂再生性能、热稳定性良好,较文献报道的保水剂吸水效果优异,可以在实际生产和生活中推广应用。

    Abstract:

    [Objective] The preparation method of superabsorbent compound by copolymerization of cellulose extracted from wheat bran with humic acid and its performance were studied in order to solve the existing problems of popular water retention agents, such as difficult to biodegrade, high cost, serious pollution, poor regeneration and others.[Methods] The composite superabsorbent compound was prepared for the first time using cellulose which was extracted from wheat bran by alkali method, with humic acid as an additive and acrylic acid as monomer by polymerization in this study. Its surface morphology and thermal stability were characterized respectively by scanning electron microscopy(SEM), thermal gravity analysis(TG). The effects of dosage on sodium hydroxide, initiator, crosslinking agent, cellulose and humic acid were investigated. Moreover, the effects of temperature, different kinds of crosslinking agents and regeneration properties were also discussed.[Results] The results indicated that:when 0.15 g of cellulose and 20 ml of acrylic were inputted, the cross-linking agent (N, N-methylene double acryl amide) would be 0.03% of acrylic, the initiator will be 0.8% of acrylic. When humic acid was 0.1 g, sodium hydroxide was 80%, the reactive temperature was 80℃, the maximum absorption rates of the superabsorbent to distilled water reached 989 g/g, to underground water and brine, the values were 120.34 g/g and 62.76 g/g.[Conclusion] The superabsorbent compound showed good thermal stability and renewable performance. In comparison with the similar products reported in relative references, it has better water absorbing properties, and could be popularized and applied in real life.

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郑艳萍,刘芳,孙看军,叶鹤琳,张丽,刘海霞.麦麸纤维素与腐植酸复合保水剂的制备及性能[J].水土保持通报,2018,38(2):253-257

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  • 收稿日期:2017-09-26
  • 最后修改日期:2017-10-15
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  • 在线发布日期: 2018-05-17
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