利用小麦秸秆制备的保水剂性能研究
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河西学院校长资助项目“以柠檬酸渣为原料生产微生态高蛋白饲料的研究”(XZ200814);甘肃省高校河西走廊特色资源利用省级重点实验室项目(XZ1014);甘肃省科技支撑计划项目(1104FKCG118)


Synthesis and Water-holding Performance of Water Retaining Agent Made from Wheat Straw
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    摘要:

    [目的] 以小麦秸秆纤维素接枝丙烯酸制备保水剂,并检测各因素对保水剂吸水性能的影响,探索制备保水剂的最佳反应条件,以期制备出成本低,降解性好,保水性高的新型保水剂。[方法] 采用水溶液聚合法制备保水剂,并通过单因素试验和正交试验来确定最佳反应条件,对合成产物的吸液倍率、保水性能和表观形态进行测定与表征。[结果] 温度为70 ℃,去离子水用量为160 ml,2.0%N,N'-亚甲基双丙烯酰胺(MBAM)用量为9 ml,引发剂(过硫酸钾:硫代硫酸钠=3∶1)与丙烯酸单体比为2.0%,丙烯酸中和度为70%,反应时间为1 h,合成的保水剂具有较高的吸水或盐水倍率,1 g保水剂吸0.9%NaCl溶液41.2 g/g,吸去离子水430.9 g/g。红外光谱分析和电镜扫描结果表明,保水剂胶体接枝聚合成功,胶体具有良好的表面形态。[结论] 制备的保水剂吸液速率快、重复吸水效果较好。保水剂在氯化铁溶液中吸水倍率最高,达到113 g/g。复合离子溶液中,在离子浓度为1 g/L时吸水倍率最高达57 g/g。

    Abstract:

    [Objective] In order to create an excellent water-holding material, using wheat straw as raw material, acrylic acid(AA) as graft monomers, the N, N'-methylene bisacrylamide as crosslinker and the potassium peroxydisulfate as free radical evocating agent, the super absorbent polymer was prepared by water solution polymerization. [Methods] The optimized reaction conditions were determined based on a single factor and an orthogonal experiment. In addition, the absorbency, retaining capacity and surface morphology of the obtained water retention agent in the experiment were characterized. [Results] Optimal reaction conditions were as follows: temperature 70 ℃, deionized water 160 ml, 2%N, N-methylene double acrylamide solution 9 ml, initiator accounted for acrylic monomer 2%, degree of neutralization of AA was 70%, reaction time was 1 h. Under this experimental conditions, the water retention agent had stronger water absorbency, and the 1 g dry super absorbent polymer can absorb water 41.2 g/g in 0.9% NaCl solution and 430.9 g/g in distilled water. The colloid graft polymerization of water retention agent was successful, and the surface morphology was good. [Conclusion] Super absorbent polymer has faster fluid and good characteristics of water retention and reuse. The product can absorb water 113 g/g in ferric chloride solution of the different ions solution and the maximum water absorption was 57 g/g in compound ion solution.

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张慧瑛,樊丹阳,卢妹妹,贾鸿娜,郝军元.利用小麦秸秆制备的保水剂性能研究[J].水土保持通报,2017,37(2):193-198

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  • 收稿日期:2016-09-19
  • 最后修改日期:2016-10-21
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  • 在线发布日期: 2017-05-10
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